Bonding and antibonding states in quantum dot molecules

This page gathers publications on coupled quantum dots and quantum dot molecules, with emphasis on atomistic studies of bonding and antibonding states, hole-state coupling, tunneling, and level reordering.

Antibonding ground states in crystal phase quantum dots

Phys. Rev. B 106, L041405 (2022)

This work shows that crystal-phase InP quantum dots can exhibit an unusual antibonding hole ground state, despite being defined within a single chemical material. It links this nonintuitive level ordering to the combined role of crystal-phase interfaces and weak strain neglected in simplified models.

Keywords: crystal-phase quantum dots

Main result: crystal-phase InP quantum dots may host an antibonding hole ground state, leaving a clear fingerprint in the excitonic spectrum. Even weak zinc-blende/wurtzite strain can qualitatively reshape the lowest hole states.

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Electric-field control of exciton fine structure in alloyed nanowire quantum dot molecules

Phys. Rev. B 104, 195411 (2021)

This work extends electric-field control of exciton fine structure to alloyed nanowire quantum-dot molecules, where alloy randomness itself becomes part of the physics. It shows that nominally identical structures can exhibit qualitatively different field evolution of excitonic spectra.

Keywords: nanowire quantum dots, quantum dot molecules, fine-structure splitting

Main result: alloy randomness can both generate and reshape fine-structure splitting in nanowire quantum-dot molecules under electric field. Yet selected realizations still allow sub-µeV splitting without losing optical activity.

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Electric field tuning of excitonic fine-structure splitting in asymmetric InAs/InP nanowire quantum dot molecules

Phys. Rev. B 100, 235417 (2019)

This work shows how electric field can be used to tune excitonic fine-structure splitting in coupled InAs/InP nanowire quantum dots. It identifies a regime where bright-exciton splitting can be reduced without simultaneously suppressing optical activity.

Keywords: nanowire quantum dots, InAs/InP, quantum dot molecules

Main result: strong interdot coupling enables electric-field tuning of bright-exciton splitting down to zero while preserving useful optical strength. This makes nanowire quantum-dot molecules attractive for entangled-photon applications.

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Atomistic theory of excitonic fine structure in InAs/InP nanowire quantum dot molecules

Phys. Rev. B 95, 125407 (2017)

This work develops an atomistic description of excitonic fine structure in coupled InAs/InP nanowire quantum dots. It shows how interdot coupling and realistic atomistic asymmetry together govern the bright-exciton doublet and polarization response.

Keywords: nanowire quantum dots, InAs/InP, quantum dot molecules, fine-structure splitting

Main result: excitonic fine structure in nanowire quantum-dot molecules is controlled jointly by coupling and atomistic symmetry breaking. A simple single-dot picture is insufficient once realistic molecular coupling is present.

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Strain effects on the electronic structure of strongly coupled self-assembled InAs/GaAs quantum dots: Tight-binding approach

Phys. Rev. B 74, 195339 (2006)

This work analyzes self-assembled quantum dots with atomistic theory, emphasizing strain, band mixing, and realistic many-body spectra. It addresses effects that are difficult to capture within simplified continuum descriptions.

Keywords: self-assembled quantum dots

Main result: quantitative agreement for self-assembled quantum-dot spectra requires realistic strain and atomistic band-structure treatment. Small structural details can qualitatively influence the low-energy states.

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Quantum Dot Molecules and Chains

in Quantum Dots: Fundamentals, Applications, and Frontiers, 257–268 (2005)

This work studies coupled quantum dots with atomistic theory, emphasizing how tunneling, strain, and valence-band complexity reshape the molecular-like spectrum. It goes beyond simple bonding–antibonding intuition whenever realistic hole physics becomes important.

Keywords: quantum dot molecules

Main result: realistic coupling in quantum-dot molecules can reorder levels and qualitatively modify the nature of the lowest hole and excitonic states. Atomistic details are essential to correctly identify bonding versus antibonding behavior.

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Coupling and Strain Effects in Vertically Stacked Double InAs/GaAs Quantum Dots: Tight-Binding Approach

Acta Phys. Pol. A 106, 193 (2004)

This work studies coupled quantum dots with atomistic theory, emphasizing how tunneling, strain, and valence-band complexity reshape the molecular-like spectrum. It goes beyond simple bonding–antibonding intuition whenever realistic hole physics becomes important.

Keywords: atomistic theory, quantum dots

Main result: realistic coupling in quantum-dot molecules can reorder levels and qualitatively modify the nature of the lowest hole and excitonic states. Atomistic details are essential to correctly identify bonding versus antibonding behavior.

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Electronic properties of quantum-dot molecules

Physica E 17, 40–41 (2003)

This work studies coupled quantum dots with atomistic theory, emphasizing how tunneling, strain, and valence-band complexity reshape the molecular-like spectrum. It goes beyond simple bonding–antibonding intuition whenever realistic hole physics becomes important.

Keywords: quantum dot molecules

Main result: realistic coupling in quantum-dot molecules can reorder levels and qualitatively modify the nature of the lowest hole and excitonic states. Atomistic details are essential to correctly identify bonding versus antibonding behavior.

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Tunnel-Coupled Quantum Dots: Atomistic Theory of Quantum Dot Molecules and Arrays

Mat. Res. Soc. Symp. Proc. 737, E1.2.1 (2003)

This work studies coupled quantum dots with atomistic theory, emphasizing how tunneling, strain, and valence-band complexity reshape the molecular-like spectrum. It goes beyond simple bonding–antibonding intuition whenever realistic hole physics becomes important.

Keywords: quantum dot molecules

Main result: realistic coupling in quantum-dot molecules can reorder levels and qualitatively modify the nature of the lowest hole and excitonic states. Atomistic details are essential to correctly identify bonding versus antibonding behavior.

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Artificial molecules

Artificial molecules (2001)

This work studies coupled quantum dots with atomistic theory, emphasizing how tunneling, strain, and valence-band complexity reshape the molecular-like spectrum. It goes beyond simple bonding–antibonding intuition whenever realistic hole physics becomes important.

Keywords: quantum dot molecules

Main result: realistic coupling in quantum-dot molecules can reorder levels and qualitatively modify the nature of the lowest hole and excitonic states. Atomistic details are essential to correctly identify bonding versus antibonding behavior.

PDF · DOI